How do propane or kerosene refrigerators work—ones that require no electricity at all and are called “ice from fire” units? — KN
Heater-based refrigerators make use of an absorption cycle in which a refrigerant is driven out of solution as a gas in a boiler, condenses into a liquid in a condenser, evaporates back into a gas in an evaporator, and finally goes back into solution in an absorption unit. The cooling effect comes during the evaporation in the evaporator because converting a liquid to a gas requires energy and thus extracts heat from everything around the evaporating liquid.
The most effective modern absorption cycle refrigerators use a solution of lithium bromide (LiBr) in water. What enters the boiler is a relatively dilute solution of LiBr (57.5%) and what leaves is dense, pure water vapor and a relatively concentrated solution of LiBr (64%). The pure water vapor enters a condenser, where it gives up heat to its surroundings and turns into liquid water. To convert this liquid water back into gas, all that has to happen is for its pressure to drop. That pressure drop occurs when the water enters a low-pressure evaporator through a narrow orifice. As the water evaporates, it draws heat from its surroundings and refrigerates them.
Finally, something must collect this low pressure water vapor and carry it back to the boiler. That “something” is the concentrated LiBr solution. When the low-pressure water vapor encounters the concentrated LiBr solution in the absorption unit, it quickly goes back into solution. The solution becomes less concentrated as it draws water vapor out of the gas above it. This diluted solution then returns to the boiler to begin the process all over again.
Overall, the pure water follows one path and the LiBr solution follows another. The pure water first appears as a high-pressure gas in the boiler (out of the boiling LiBr solution), converts to a liquid in the condenser, evaporates back into a low-pressure gas in the evaporator, and finally disappears in the absorption unit (into the cool LiBr solution). Meanwhile, the LiBr solution shuttles back and forth between the boiler (where it gives up water vapor) and the absorption unit (where it picks up water vapor). The remarkable thing about this whole cycle is that its only moving parts are in the pump that moves LiBr solution from the absorption unit to the boiler. Its only significant power source is the heater that operates the boiler. That heater can use propane, kerosene, electricity, waste heat from a conventional power plant, and so on.